Sunday, February 28
- 4:00 pm - Chair's reception, Harborview Room
- 6:00 pm - Dinner
Sunday Evening | Atom-transfer Reactions |
Chair: James M. Mayer, University of Washington
- Henry Taube, Stanford University
7:30-8:00 pm - Introductory Remarks
- James H. Espenson, Iowa State University
8:10-8:50 pm - Atom-Transfer Reactions Catalyzed by Methyltrioxorhenium
- Christopher C. Cummins, Massachusetts Institute of Technology
9:00-9:40 pm - Nitrido-Bridged Intermediates in Intermetal N-atom Transfer and New N-atom Abstraction Reactions
Monday, March 1
- 8:30 am - Conference Photo
Monday Morning | Atom-Transfer; Conformationally-Controlled Electron Transfer Reactions |
Chair: David M. Stanbury, Auburn University
- Thomas J. Meyer, University of North Carolina
9:00-9:45 am - Atom-Transfer Reactions of Os(VI)-Nitridos
- 10:00-10:30 am - Break
- David B. Rorabacher, Wayne State University
10:30-11:15 am - Gates and Stepladders in Conformationally-Controlled Electron Transfer
- Harry B. Gray, California Institute of Technology
11:30 am-12:15 pm - Substrates for Rapid Delivery of Electrons and Holes to Buried Active Sites of Metalloenzymes
- 12:30 pm - Lunch
Monday Afternoon 4:30-6:00 pm | Poster Session |
Monday Evening | Organometallic Mechanisms |
Chair: Jack R. Norton, Columbia University
- John E. Bercaw, California Institute of Technology
7:30-8:15 pm - Mechanisms of Stereocontrol in Metallocene-Catalyzed Polymerizations of Propylene
- Ian P. Rothwell, Purdue University
8:30-9:15 pm - Mechanistic Studies of the 4-Electron Reduction of Small Molecules by Tungsten Aryloxides
Tuesday, March 2
Tuesday Morning | Organometallic Mechanisms |
Chair: William D. Jones II, University of Rochester
- Alan S. Goldman, Rutgers University
8:45-9:30 am - Transition Metal Catalyzed Alkane Dehydrogenation
- 9:45-10:15 am - Break
- Roy A. Periana, Catalytica Advanced Technologies, Inc.
10:15-11:00 am - High Yield Oxidation of Methane to Methanol with CH Activation Platinum Catalysts: Chemistry and Mechanism
- Karen I. Goldberg, University of Washington
11:15 am-12:00 pm - Reductive Elimination and Oxidative Addition Reactions Involving C-C, C-H, and C-X Bonds at Pt(IV)/Pt(II)
- 12:30 pm - Lunch
Tuesday Afternoon 4:30-6:00 pm | Poster Session |
Tuesday Evening | Olefin Exchange Processes and Bioinorganic Mechanisms |
Chair: Alison Butler, University of California, Santa Barbara
- Lars I. Elding, Lund University, Sweden
7:30-8:15 pm - Olefin and Phosphine Exchange Processes at Platinum(II) Complexes
- Alvin L. Crumbliss, Duke University
8:30-9:15 pm - Mechanisms of Biologically Relevant Reactions at Iron Centers
Wednesday, March 3
Wednesday Morning | Bioinorganic Mechanisms |
Chair: William H. Woodruff, Los Alamos National Laboratory
- Ólöf Einarsdóttir, University of California, Santa Cruz
8:45-9:30 am - The Mechanism of Oxygen Reduction by Cytochrome c Oxidase: Time-Resolved Optical Absorption Study
- 9:45-10:15 am - Break
- Gerald T. Babcock, Michigan State University
10:15-11:00 am - Oxygen-Oxygen Bond Formation and Cleavage in Respiration and Photosynthesis
- David A. Wink, National Cancer Institute
11:15 am-12:00 pm - Mechanism of Reactive Nitrogen Oxide Species in Balance between Oxidative and Nitrosative Stress
- 12:30 pm - Lunch
Wednesday Evening | Reactions of Nitric Oxide and Peroxynitrite: Some Biological Implications |
Chair: Peter Lay, University of Sydney
- James K. Hurst, Washington State University
7:30-8:15 pm - Oxidative Chemistry of Peroxynitrite and Its Biological Implications
- Willem H. Koppenol, ETH, Switzerland
8:30-9:15 pm - The Carbon Dioxide Adduct of Peroxynitrite, 1-Carboxy-2-nitrosodioxidane: A Pulse Radiolysis Investigation
Wednesday Evening 9:30-11:00 pm | Poster Session |
Thursday, March 4
Thursday Morning | Reactions of Nitric Oxide and Peroxynitrite: Some Biological Implications |
Chair: William C. Trogler, University of California, San Diego
- Judith N. Burstyn, University of Wisconsin
8:45-9:15 am - NO and CO as Biological Signal Transducers: Allosteric Regulation through Coordination-Sphere Reorganization
- 9:45-10:15 am - Break
- Scott D. Bohle, University of Wyoming
10:15-11:00 am - Superoxide Independent Formation of Peroxynitrite
- Peter C. Ford, University of California, Santa Barbara
11:15 am-12:00 pm - Mechanisms of Metal-Nitrosyl Bond Formation and Breaking
- 12:30 pm - Lunch
Chair: Dale W. Margerum, Purdue University
- 8:00 pm - Business Meeting
- Ralph G. Wilkins, New Mexico State University
8:30 pm - Fifty Years of Fun with Inorganic Reaction Mechanisms
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