Sunday |
4:00 pm - 8:00 pm | Arrival and Check-in |
6:00 pm | Dinner |
7:30 pm - 7:40 pm | Welcome / Introductory Comments by GRC Site Staff |
7:40 pm - 9:30 pm | Mechanism as a Tool to
Control Reactivity and Selectivity |
| Discussion Leader: John Bercaw (California Institute of Technology, USA) |
7:40 pm - 7:50 pm | Opening Remarks |
7:50 pm - 8:25 pm | Guy Lloyd-Jones (University of Edinburgh, United Kingdom) "(Re)agent Provocateur" |
8:25 pm - 8:40 pm | Discussion |
8:40 pm - 9:15 pm | Robert Knowles (Princeton University, USA) "Proton-Coupled
Electron Transfer in Organic Synthesis and Asymmetric Catalysis" |
9:15 pm - 9:30 pm | Discussion |
Monday |
7:30 am - 8:30 am | Breakfast |
8:30 am | Group Photo |
9:00 am - 12:30 pm | Mechanism as Applied
to Synthetic Methods |
| Discussion Leader: Sebastien Monfette (Pfizer, USA) |
9:00 am - 9:30 am | David Collum (Cornell University, USA) "Structure-Reactivity Relationships in Lithium Enolates" |
9:30 am - 9:45 am | Discussion |
9:45 am - 10:15 am | Kyoko Nozaki (University of Tokyo, Japan) "Mechanistic Studies
on the Pd-Catalyzed Copolymerization of Ethylene with Polar Monomers" |
10:15 am - 10:30 am | Discussion |
10:30 am - 11:00 am | Coffee Break |
11:00 am - 11:30 am | Yi Xiao (Bristol-Myers Squibb, USA) "Catalysis in the
Pharmaceutical Industry: Challenges and Approaches" |
11:30 am - 11:45 am | Discussion |
11:45 am - 12:15 pm | Gregory Whiteker (Dow AgroSciences, USA) "Applications of Rhodium-Catalyzed Hydroformylation" |
12:15 pm - 12:30 pm | Discussion |
12:30 pm | Lunch |
1:30 pm - 4:00 pm | Free Time |
4:00 pm - 6:00 pm | Poster Session |
6:00 pm | Dinner |
7:30 pm - 9:30 pm | Mechanisms for Understanding
Coordination Chemistry |
| Discussion Leader: Francois Gabbai (Texas A&M University, USA) |
7:30 pm - 8:00 pm | Bas DeBruin (University of Amsterdam, The Netherlands) "Reactivity of Nitrogen- and Carbon-Centered Ligand Radicals" |
8:00 pm - 8:15 pm | Discussion |
8:15 pm - 8:45 pm | Nathaniel Szymczak (University of Michigan, USA) "Another Knob to Dial: Moving Beyond a Metal’s Primary Coordination Sphere" |
8:45 pm - 9:00 pm | Discussion |
9:00 pm - 9:10 pm | Ian Tonks (University of Minnesota, USA) "Catalytic Formal [2+2+1] Synthesis of Pyrroles from Alkynes and Diazenes via Ti(II)/Ti(IV) Redox Catalysis" |
9:10 pm - 9:15 pm | Discussion |
9:15 pm - 9:25 pm | Jeffery Byers (Boston College, USA) "Mechanistic Insight into Solvent-Dependent Linker Exchange Reactions in Metal Organic Frameworks" |
9:25 pm - 9:30 pm | Discussion |
Tuesday |
7:30 am - 8:30 am | Breakfast |
9:00 am - 12:30 pm | Mechanisms in Bioinorganic
Chemistry |
| Discussion Leader: Justine Roth (Johns Hopkins University, USA) |
9:00 am - 9:30 am | Serena Debeer (Max Planck Institute for Chemical Energy Conversion, Germany) "Spectroscopic
Insights into Small Molecule Activation in Biological Systems" |
9:30 am - 9:45 am | Discussion |
9:45 am - 10:15 am | Andrew Borovik (University of California, Irvine, USA) "Probing the Role of Metal-Oxo and Metal-Hydroxo Complexes in Small Molecule Activation" |
10:15 am - 10:30 am | Discussion |
10:30 am - 11:00 am | Coffee Break |
11:00 am - 11:30 am | Amy Rosenzwig (Northwestern University, USA) "Biological Methane Oxidation" |
11:30 am - 11:45 am | Discussion |
11:45 am - 12:15 pm | Michael Green (University of California, Irvine, USA) "A Ligand Protection Scheme for Metal-Oxo Driven C-H Bond Activations: Insights from
P450 Catalysis" |
12:15 pm - 12:30 pm | Discussion |
12:30 pm | Lunch |
1:30 pm - 4:00 pm | Free Time |
4:00 pm - 6:00 pm | Poster Session |
6:00 pm | Dinner |
7:30 pm - 9:30 pm | Mechanisms for
Renewable Energy |
| Discussion Leader: Cathleen Crudden (Queen's University, Canada) |
7:30 pm - 8:00 pm | Kyoung-Shin Choi (University of Wisconsin-Madison, USA) "Electrochemical and
Photoelectrochemical Biomass Conversion" |
8:00 pm - 8:15 pm | Discussion |
8:15 pm - 8:45 pm | Clifford Kubiak (University of California, San Diego, USA) "Mechanistic Studies of the Electrocatalytic Reduction of CO2: Supramolecular Approaches to Lowering the Overpotential" |
8:45 pm - 9:00 pm | Discussion |
9:00 pm - 9:10 pm | Iraklis Pappas (Princeton University, USA) "Hydrogen Atom Transfer as a Means for Dinitrogen Functionalization in the Coordination Sphere of Group 4 Metals" |
9:10 pm - 9:15 pm | Discussion |
9:15 pm - 9:25 pm | Andrew Sutton (Los Alamos National Laboratory, USA) "Adding Value to Biomass - Green Gold!" |
9:25 pm - 9:30 pm | Discussion |
Wednesday |
7:30 am - 8:30 am | Breakfast |
9:00 am - 12:30 pm | Mechanisms in Materials and Catalysis |
| Discussion Leader: Brooke Small (Chevron Phillips Chemical, USA) |
9:00 am - 9:30 am | Mircea Dinca (Massachusetts Institute of Technology, USA) "Mechanistic
Insights in Cation Exchange and Small Molecule Reactivity in MOFs" |
9:30 am - 9:45 am | Discussion |
9:45 am - 10:15 am | Michael Reynolds (Shell Exploration and Production Company, USA) "Novel Unsupported
Catalysts for Upgrading Heavy Oil" |
10:15 am - 10:30 am | Discussion |
10:30 am - 11:00 am | Coffee Break |
11:00 am - 11:30 am | Alison Fout (University of Illinois at Urbana-Champaign, USA) "Mechanistic Studies of Nitrite Reduction by a Non-Heme Iron Complex" |
11:30 am - 11:45 am | Discussion |
11:45 am - 12:15 pm | Mahdi Abu-Omar (Purdue University, USA) "Mechanistic Aspects
of Sustainable Catalytic Conversions" |
12:15 pm - 12:30 pm | Discussion |
12:30 pm | Lunch |
1:30 pm - 4:00 pm | Free Time |
4:00 pm - 6:00 pm | Poster Session |
6:00 pm | Dinner |
7:00 pm - 7:30 pm | Business Meeting |
| Nominations for the Next Vice Chair; Fill in Conference Evaluation Forms; Discuss Future Site and Scheduling Preferences; Election of the Next Vice Chair |
7:30 pm - 9:30 pm | Mechanisms in Electrocatalysis and Nanoscience |
| Discussion Leader: Laurel Schafer (University of British Columbia, Canada) |
7:30 pm - 8:00 pm | Jenny Yang (University of California, Irvine, USA) "Thermodynamic
Considerations in the Design of Molecular Electrocatalysts for Proton and CO2
Reduction" |
8:00 pm - 8:15 pm | Discussion |
8:15 pm - 8:45 pm | Brandi Cossiart (University of Washington, USA) "Metal Phosphide Quantum Dots: Mechanisms of Precursor Conversion, Nucleation and Growth" |
8:45 pm - 9:00 pm | Discussion |
9:00 pm - 9:10 pm | Christopher Caputo (University of Toronto, Canada) "Development of Fluorophosphonium Lewis Acids - Applications in Hydrodefluorination, Hydrosilylation and Dehydrocoupling Catalysis" |
9:10 pm - 9:15 pm | Discussion |
9:15 pm - 9:25 pm | Jennifer Obligacion (Princeton University, USA) "Insights into the Mechanism of Cobalt-Catalyzed Carbon-Boron Bond Forming Reactions" |
9:25 pm - 9:30 pm | Discussion |
Thursday |
7:30 am - 8:30 am | Breakfast |
9:00 am - 12:30 pm | Mechanisms in Organometallic Chemistry and Small Molecule Activation |
| Discussion Leader: Suzanne Bart (Purdue University, USA) |
9:00 am - 9:30 am | Timothy Warren (Georgetown University, USA) "Copper-Catalyzed
C-H Functionalization: Mechanistic Insights Aid Method Development" |
9:30 am - 9:45 am | Discussion |
9:45 am - 10:15 am | Enrique Batista (Los Alamos National Laboratory, USA) "Reaction Mechanism
for Nitrogen Reduction to Ammonia" |
10:15 am - 10:30 am | Discussion |
10:30 am - 11:00 am | Coffee Break |
11:00 am - 11:30 am | Ian Stewart (ExxonMobil, USA) "Sequence Control in Olefin Polymerization" |
11:30 am - 11:45 am | Discussion |
11:45 am - 12:15 pm | Milton Smith (Michigan State University, USA) "The
Interplay Between Experiment and Theory in C–H Borylation" |
12:15 pm - 12:30 pm | Discussion |
12:30 pm | Lunch |
1:30 pm - 4:00 pm | Free Time |
4:00 pm - 6:00 pm | Poster Session |
6:00 pm | Dinner |
7:30 pm - 9:30 pm | Mechanisms in
Catalysis |
| Discussion Leader: Robert Bergman (University of California, Berkeley, USA) |
7:30 pm - 7:45 pm | Ilija Coric (Yale University, USA) "Binding of Nitrogenase Substrates to an Iron Complex with Sulfur and Carbon Ligands" |
7:45 pm - 7:50 pm | Discussion |
7:50 pm - 8:05 pm | Christina Li (Stanford University, USA) "Probing the Active Site for CO Reduction on Oxide-Derived Copper Electrocatalysts" |
8:05 pm - 8:10 pm | Discussion |
8:10 pm - 8:25 pm | Aaron Sattler (ExxonMobil, USA) "Development of Supported Catalysts for Olefin Trimerization Catalysis" |
8:25 pm - 8:30 pm | Discussion |
8:30 pm - 9:15 pm | Keynote: John Hartwig (University of California, Berkeley, USA) "Mechanism and
Design of Catalytic Processes for Organic Synthesis" |
9:15 pm - 9:30 pm | Discussion |
Friday |
7:30 am - 8:30 am | Breakfast |
9:00 am | Departure |