Sunday |
2:00 pm - 9:00 pm | Arrival and Check-in |
6:00 pm | Dinner |
7:30 pm - 7:40 pm | Welcome / Introductory Comments by GRC Site Staff |
7:40 pm - 9:30 pm | Small
Molecule Activation |
| Discussion Leader: John Gordon (Los Alamos National Laboratory, USA) |
7:40 pm - 7:50 pm | Opening Remarks |
7:50 pm - 8:20 pm | Sven Schneider (University of Goettingen, Germany) "Dinitrogen Functionalization via N2-Splitting: The Relevance of Spin-States" |
8:20 pm - 8:35 pm | Discussion |
8:35 pm - 9:05 pm | Karen Goldberg (University of Washington, USA) "Oxygen and Organometallics and Oxidations! Oh My!" |
9:05 pm - 9:20 pm | Discussion |
9:20 pm - 9:30 pm | General Discussion |
Monday |
7:30 am - 8:30 am | Breakfast |
9:00 am - 12:30 pm | Organometallics and Organic
Synthesis |
| Discussion Leader: Patrick Holland (Yale University, USA) |
9:00 am - 9:30 am | Guosheng Liu (Shanghai Institute of Organic Chemistry, China) "Copper-Catalyzed Enantioselective Radical Reaction in Difunctionalization of Alkenes" |
9:30 am - 9:45 am | Discussion |
9:45 am - 10:15 am | Guy Lloyd-Jones (University of Edinburgh, United Kingdom) "Mechanisms of Release, Decomposition, and Coupling of R-B and R-Si Reagents" |
10:15 am - 10:30 am | Discussion |
10:30 am - 11:00 am | Coffee Break |
11:00 am - 11:30 am | Abigail Doyle (Princeton University, USA) "Direct Csp3-H Cross Coupling Enabled by Nickel and Photoredox Catalysis" |
11:30 am - 11:45 am | Discussion |
11:45 am - 12:15 pm | James Morken (Boston College, USA) "Catalytic Conjunctive Cross-Coupling" |
12:15 pm - 12:30 pm | Discussion |
12:30 pm | Lunch |
1:30 pm - 4:00 pm | Free Time |
4:00 pm - 6:00 pm | Poster Session |
6:00 pm | Dinner |
7:30 pm - 9:30 pm | Main
Group Organometallics |
| Discussion Leader: Mitch Smith (Michigan State University, USA) |
7:30 pm - 8:00 pm | R. Tom Baker (University of Ottawa, Canada) "Losing the Precious: Base Metal Catalysis for OrganofluorineTransformations" |
8:00 pm - 8:10 pm | Discussion |
8:10 pm - 8:40 pm | Christopher Cummins (Massachusetts Institute of Technology, USA) "Reactive Intermediates from Molecular Precursors" |
8:40 pm - 8:50 pm | Discussion |
8:50 pm - 9:20 pm | Gregory Robinson (University of Georgia, USA) "Stabilization of Elusive Main Group Oxides: Oxidation of Carbene-Stabilized Diatomics" |
9:20 pm - 9:30 pm | Discussion |
Tuesday |
7:30 am - 8:30 am | Breakfast |
8:30 am | Group Photo |
9:00 am - 12:30 pm | Catalysis and Commodities |
| Discussion Leader: Matthew Christianson (The Dow Chemical Company, USA) |
9:00 am - 9:30 am | Ruth Figueroa (Dow Chemical Company, USA) "Design and Development of Molecular Catalysts for High Temperature Ethylene-α-Olefin Copolymerization Reactions" |
9:30 am - 9:45 am | Discussion |
9:45 am - 10:15 am | Roy Periana (The Scripps Research Institute, USA) "Mechanism of Selective Oxy-Functionalization of Alkanes with Main Group Electrophiles" |
10:15 am - 10:30 am | Discussion |
10:30 am - 11:00 am | Coffee Break |
11:00 am - 11:30 am | Alceo Macchioni (University of Perugia, Italy) "Organometallic Chemistry, the Hero of Two Worlds: From Olefin Polymerization to Water Oxidation Catalysts" |
11:30 am - 11:45 am | Discussion |
11:45 am - 12:15 pm | Patrick Brant (ExxonMobil, USA) "Precise Control of Polyolefin Chain Ends Enables Design of New Materials" |
12:15 pm - 12:30 pm | Discussion |
12:30 pm | Lunch |
1:30 pm - 4:00 pm | Free Time |
4:00 pm - 6:00 pm | Poster Session |
6:00 pm | Dinner |
7:30 pm - 9:30 pm | Ligand
Design |
| Discussion Leader: Nilay Hazari (Yale University, USA) |
7:30 pm - 8:00 pm | Jorg Eppinger (King Abdullah University of Science and Technology (KAUST), Saudi Arabia) "Merging Biological and Organometallic Catalysis: Emerging Tools for Organic Synthesis" |
8:00 pm - 8:10 pm | Discussion |
8:10 pm - 8:40 pm | Alexander Miller (University of North Carolina at Chapel Hill, USA) "Cation-Responsive Pincer-Crown Ether Catalysts" |
8:40 pm - 8:50 pm | Discussion |
8:50 pm - 9:05 pm | Jonathan Axtell (University of California, Los Angeles, USA) "B12(OR)12 Reagents as Tunable One Electron Oxidants" |
9:05 pm - 9:10 pm | Discussion |
9:10 pm - 9:25 pm | Diana Iovan (Harvard University, USA) "Characterization of Iron-Imido Species Relevant to N-Group Transfer Chemistry" |
9:25 pm - 9:30 pm | Discussion |
Wednesday |
7:30 am - 8:30 am | Breakfast |
9:00 am - 12:30 pm | Chemistry of Early Metals and
the F-Block |
| Discussion Leader: Christine Thomas (Brandeis University, USA) |
9:00 am - 9:30 am | Aaron Odom (Michigan State University, USA) "Quantification of Ligand Effects in High Valent Catalysis" |
9:30 am - 9:45 am | Discussion |
9:45 am - 10:15 am | Polly Arnold (University of Edinburgh, United Kingdom) "Dinuclear f-Block Architectures for Multiple Electron Reductive Activation Chemistry" |
10:15 am - 10:30 am | Discussion |
10:30 am - 11:00 am | Coffee Break |
11:00 am - 11:30 am | Stosh Kozimor (Los Alamos National Laboratory, USA) "Reactivity of +3 Actinides" |
11:30 am - 11:45 am | Discussion |
11:45 am - 12:00 pm | Ian Tonks (University of Minnesota, USA) "New Advances in Ti-Catalyzed Nitrene Transfer: Selective Three Component Coupling Reactions" |
12:00 pm - 12:05 pm | Discussion |
12:05 pm - 12:20 pm | Matthew Whited (Carleton College, USA) "Stoichiometric and Catalytic Reactions Exploiting Metal/Silicon Cooperation" |
12:20 pm - 12:25 pm | Discussion |
12:25 pm - 12:30 pm | General Discussion |
12:30 pm | Lunch |
1:30 pm - 4:00 pm | Free Time |
4:00 pm - 6:00 pm | Poster Session |
6:00 pm | Dinner |
7:00 pm - 7:30 pm | Business Meeting |
| Nominations for the Next Vice Chair; Fill in Conference Evaluation Forms; Discuss Future Site and Scheduling Preferences; Election of the Next Vice Chair |
7:30 pm - 9:30 pm | Materials and Organometallics |
| Discussion Leader: Smaranda Marinescu (University of Southern California, USA) |
7:30 pm - 8:00 pm | Anne McNeil (University of Michigan, USA) "Talking Lions and Catalyst Transfer Polycondensations" |
8:00 pm - 8:10 pm | Discussion |
8:10 pm - 8:40 pm | Jonathan Owen (Columbia University, USA) "Kinetics and Mechanism of Quantum Dot Nucleation and Growth" |
8:40 pm - 8:50 pm | Discussion |
8:50 pm - 9:20 pm | Lisa McElwee-White (University of Florida, USA) "Mechanism Based Design of Organometallic Precursors for Deposition of Metal Nanostructures" |
9:20 pm - 9:30 pm | Discussion |
Thursday |
7:30 am - 8:30 am | Breakfast |
9:00 am - 12:30 pm | Reaction Mechanisms |
| Discussion Leader: Douglas Grotjahn (San Diego State University, USA) |
9:00 am - 9:30 am | Eric Clot (CNRS, France) "DFT Studies of Homogeneous Catalytic Reactions: Cu-Catalyzed Formation of Amides from Alcohol and Amine" |
9:30 am - 9:45 am | Discussion |
9:45 am - 10:15 am | Christophe Coperet (ETH Zurich, Switzerland) "Some Magic and Pitfalls of Activating Molecular Systems on Surfaces" |
10:15 am - 10:30 am | Discussion |
10:30 am - 11:00 am | Coffee Break |
11:00 am - 11:30 am | John Berry (University of Wisconsin-Madison, USA) "Nitrene Transfer Catalysis: Correlating Electronic Structure with Reactivity" |
11:30 am - 11:45 am | Discussion |
11:45 am - 12:00 pm | Christopher Uyeda (Purdue University, USA) "Catalytic Reactions at Metal-Metal Bonds" |
12:00 pm - 12:05 pm | Discussion |
12:05 pm - 12:20 pm | Anna Brezny (University of Wisconsin-Madison, USA) "Kinetics of Rhodium Bis(Diazaphospholane)-Catalyzed Hydroformylation of Styrene by Use of Operando Spectroscopy" |
12:20 pm - 12:25 pm | Discussion |
12:25 pm - 12:30 pm | General Discussion |
12:30 pm | Lunch |
1:30 pm - 4:00 pm | Free Time |
4:00 pm - 6:00 pm | Poster Session |
6:00 pm | Dinner |
7:30 pm - 9:30 pm | Keynote Session: How Organometallic Chemistry Serves Society |
| Discussion Leader: Seth Brown (University of Notre Dame, USA) |
7:30 pm - 8:10 pm | Richard Schrock (Massachusetts Institute of Technology, USA) "It Ain't Over 'Til It's Over" |
8:10 pm - 8:25 pm | Discussion |
8:25 pm - 9:05 pm | Robert Crabtree (Yale University, USA) "Late Transition Metal Catalysts, Energy, and Biomass" |
9:05 pm - 9:20 pm | Discussion |
9:20 pm - 9:30 pm | Closing Remarks |
Friday |
7:30 am - 8:30 am | Breakfast |
9:00 am | Departure |