Sunday
2:00 pm - 9:00 pm
Arrival and Check-in
6:00 pm - 7:00 pm
Dinner
7:30 pm - 7:40 pm
Introductory Comments by GRC Site Staff / Welcome from the GRC Chair
7:40 pm - 9:30 pm
Organometallics in Polymer Chemistry
Discussion Leader: Christine Thomas (Brandeis University, USA)
7:40 pm - 7:50 pm
Opening Remarks
7:50 pm - 8:20 pm
Rinaldo Poli (Laboratoire de Chimie de Coordination , France)
"Organometallic Mediated Radical Polymerization (OMRP): The Importance of Making and Breaking Metal-Carbon Bonds"
8:20 pm - 8:35 pm
Discussion
8:35 pm - 9:05 pm
Jeffery Byers (Boston College, USA)
"Using Dynamic and Switchable Polymerization Catalysts to Diversify a Degradable Polymer"
9:05 pm - 9:20 pm
Discussion
9:20 pm - 9:30 pm
General Discussion
Monday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Transition Metal Based Organometallics in Synthesis and Catalysis
Discussion Leader: Michael Chetcuti (University of Strasbourg, France)
9:00 am - 9:30 am
Michael Neidig (University of Rochester, USA)
"Intermediates and Mechanism in Iron Catalyzed C-C Bond Formation"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
Susumu Saito (Nagoya University, Japan)
"Catalytic Hydrogenation of Carboxylic Acids Using Low- and High-Valent Transition Metal Complexes"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
Ryan Trovitch (Arizona State University, USA)
"Preparation and Reactivity of Phosphine-Substituted Bis(imino)pyridine and Diimine Molybdenum Compounds"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
Massimiliano Delferro (Argonne National Laboratory, USA)
"On the Mechanism of Organo-Platinum Deposition: Effects of Synthesis Techniques on Active Site Nuclearities and Catalytic Nitroaryl Hydrogenation Selectivity"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
3:00 pm - 4:00 pm
Power Hour
The GRC Power Hour is an optional informal gathering open to all meeting participants. It is designed to help address the challenges women face in science and support the professional growth of women in our communities by providing an open forum for discussion and mentoring.
Organizer: Christine Thomas (Brandeis University, USA)
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Computational Chemistry and Reaction Mechanisms
Discussion Leader: David Dixon (The University of Alabama, USA)
7:30 pm - 8:00 pm
Agusti Lledos (Autonomous University of Barcelona, Spain)
"Radical Pathways in Organometallic Chemistry: A Mechanistic Picture"
8:00 pm - 8:10 pm
Discussion
8:10 pm - 8:40 pm
Sebastian Kozuch (Ben-Gurion University of the Negev, Israel)
"On the Significance of the Energy Representation for Catalytic Cycles. Simpler, Physically Correct, and More Elegant"
8:40 pm - 8:50 pm
Discussion
8:50 pm - 9:20 pm
Ilya Gridnev (Tohoku University, Japan)
"Are There Any Reasons to Study Reaction Mechanisms?"
9:20 pm - 9:30 pm
Discussion
Tuesday
7:30 am - 8:30 am
Breakfast
8:30 am - 9:00 am
Group Photo
9:00 am - 12:30 pm
Energy and Sustainability
Discussion Leader: Mahdi Abu-Omar (University of California, Santa Barbara, USA)
9:00 am - 9:30 am
Marcel Schlaf (University of Guelph, Canada)
"Hydrodeoxygenation of Biomass Derived Sugars and Sugar Condensates into Value Added Chemicals and Fuels"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
Morris Bullock (Pacific Northwest National Laboratory, USA)
"Making and Breaking NH and NN Bonds with Mo and Fe Complexes"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
Louise Berben (University of California, Davis, USA)
"C-H Bond Formation with CO2 : Insights on Selectivity and Mechanism from Molecular Iron Electrocatalysts"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
Jeffrey Pietryga (Los Alamos National Laboratory, USA)
"Using Ligands to Optimize the Form and Function of Solar-Relevant Semiconductor Nanocrystals"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
New Reactivity and Transformations
Discussion Leader: Chip Nataro (Lafayette College, USA)
7:30 pm - 8:00 pm
David Laitar (Dow Chemical Company, USA)
"Chromium-Catalyzed Ethylene Tetramerization Using Phospholane-Based Ligands"
8:00 pm - 8:10 pm
Discussion
8:10 pm - 8:40 pm
Travis Williams (University of Southern California, USA)
"New Catalytic Architectures for Acceptorless Dehydrogenation"
8:40 pm - 8:50 pm
Discussion
8:50 pm - 9:05 pm
Aaron Vannucci (University of South Carolina, USA)
"Catalytic Photoredox C-C and C-N Cross-Couplings"
9:05 pm - 9:10 pm
Discussion
9:10 pm - 9:25 pm
Tulay Atesin (The University of Texas Rio Grande Valley, USA)
"It Is Not Just up to the Substrate: Palladium(0) Cyclizes Nazarov Substrates Through Intramolecular Allylic Alkylation"
9:25 pm - 9:30 pm
Discussion
Wednesday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Early Metal and f-Block Chemistry
Discussion Leader: Alfred Sattelberger (Argonne National Laboratory, USA)
9:00 am - 9:30 am
Jun Okuda (RWTH Aachen University, Germany)
"Molecular Hydrides of Very Early Metals"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
Marinella Mazzanti (Ecole Polytechnique Federale de Lausanne , Switzerland)
"Activation and Functionalization of Small Molecules by Multimetallic Uranium Complexes"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
Stephen Liddle (University of Manchester, United Kingdom)
"Recent Advances in Triamido-Supported Actinide-Ligand Multiple Bonding"
11:30 am - 11:45 am
Discussion
11:45 am - 12:00 pm
Pavel Dub (Los Alamos National Laboratory, USA)
"What Does the Revised Mechanism of the Noyori Hydrogenation Reaction Mean for Future Catalyst Design?"
12:00 pm - 12:05 pm
Discussion
12:05 pm - 12:20 pm
David Mills (The University of Manchester, United Kingdom)
"Thorium Redox Chemistry and a New Way to Measure Covalency by Pulsed EPR Spectroscopy"
12:20 pm - 12:25 pm
Discussion
12:25 pm - 12:30 pm
General Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:00 pm - 7:30 pm
Business Meeting
Nominations for the Next Vice Chair; Fill in Conference Evaluation Forms; Discuss Future Site and Scheduling Preferences; Election of the Next Vice Chair
7:30 pm - 9:30 pm
Ligand Platforms
Discussion Leader: Marina Petrukhina (University at Albany, SUNY, USA)
7:30 pm - 8:00 pm
Guy Bertrand (University of California, San Diego, USA)
"Stable Carbenes and Related Species as Powerful Tools in Organometallic Chemistry"
8:00 pm - 8:10 pm
Discussion
8:10 pm - 8:40 pm
Antonio Mezzetti (ETH Zurich, Switzerland)
"Base-Metal Enantioselective Catalysts with Chiral P/N Macrocyclic and Pincer Ligands"
8:40 pm - 8:50 pm
Discussion
8:50 pm - 9:20 pm
Geoff Cloke (University of Sussex, United Kingdom)
"Small Molecule Activation Across a Ti=Ti Double Bond"
9:20 pm - 9:30 pm
Discussion
Thursday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Main Group Organometallic Chemistry
Discussion Leader: Gerard Parkin (Columbia University, USA)
9:00 am - 9:30 am
Mitch Smith (Michigan State University, USA)
"C-H Borylation: Will the Road Go on Forever?"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
Eva Hevia (University of Strathclyde, United Kingdom)
"Towards a Paradigm Shift in Main Group Polar Organometallic Chemistry"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
Douglas Stephan (University of Toronto, Canada)
"Applications of FLP and Lewis Acid Catalysis"
11:30 am - 11:45 am
Discussion
11:45 am - 12:00 pm
Lisa Vondung (Philipps-Universitaet Marburg, Germany)
"Ambireactive Boron Based Donor Groups in Iron Complexes: Enabling Different Catalytic Processes by Variation of Temperature and Metal Oxidation State"
12:00 pm - 12:05 pm
Discussion
12:05 pm - 12:20 pm
William Harman (University of California, Riverside, USA)
"Redox Active Boranes as Ligands and Platforms for Small Molecule Activation"
12:20 pm - 12:25 pm
Discussion
12:25 pm - 12:30 pm
General Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
New Chemistries from Old Elements
Discussion Leader: Janis Louie (University of Utah, USA)
7:30 pm - 8:10 pm
Melanie Sanford (University of Michigan, USA)
"Organometallic Chemistry of Nickel(III) and Nickel(IV)"
8:10 pm - 8:25 pm
Discussion
8:25 pm - 9:05 pm
Peter Wolczanski (Cornell University, USA)
"Recent Adventures in the First Row of the Transition Elements"
9:05 pm - 9:20 pm
Discussion
9:20 pm - 9:30 pm
Closing Remarks
Friday
7:30 am - 8:30 am
Breakfast
9:00 am
Departure