Sunday
2:00 pm - 9:00 pm
Arrival and Check-in
6:00 pm - 7:00 pm
Dinner
7:30 pm - 7:40 pm
Introductory Comments by GRC Site Staff / Welcome from the GRC Chair
7:40 pm - 9:30 pm
Bioorganometallic and Organometallic Chemistry
7:40 pm - 8:15 pm
"Prebiotic Chemistry in a Metalloprotein Model of Acetyl Coenzyme A Synthase"
8:15 pm - 8:30 pm
Discussion
8:30 pm - 9:05 pm
"The Grignard Reagent and Reaction: A Cold Case With New Insights From Computations"
9:05 pm - 9:20 pm
Discussion
9:20 pm - 9:30 pm
General Discussion
Monday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Late and Heavy Metal Chemistry
9:00 am - 9:30 am
"From Iron to Neptunium: Using Metals To Impart Selectivity on Ligand Synthesis"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Fishing with Carborane Anions: New Ligand Platforms and Directions"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Taming Nitrene Reactivity with Silver Catalysts"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
"Organometallic Catalysts and Intermediates in CH and CC Bond Cleavage for Deconstructive Upcycling of Polyolefins"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
3:00 pm - 4:00 pm
The GRC Power Hour™
The GRC Power Hour™ is designed to address diversity and inclusion in the scientific workplace by providing a safe environment for informal and meaningful conversations amongst colleagues of all career stages. The program supports the professional growth of all members of our communities, including ethnicity, race and/or gender identity by providing an open forum for discussion and mentoring.
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Harnessing Photons and Electrons
7:30 pm - 8:00 pm
"Metal Cluster Electrocatalysts For Fast and Selective Solar Fuels Chemistry"
8:00 pm - 8:10 pm
Discussion
8:10 pm - 8:40 pm
"Electrical Polarization Controls Heterogeneous Hydride Transfer Reactivity"
8:40 pm - 8:50 pm
Discussion
8:50 pm - 9:20 pm
"Harnessing Photons and Electrons for Farmers: Only?"
9:20 pm - 9:30 pm
Discussion
Tuesday
7:30 am - 8:30 am
Breakfast
8:30 am - 9:00 am
Group Photo
9:00 am - 12:30 pm
Synthesis and Catalysis with More Abundant Metals
9:00 am - 9:30 am
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"New Cycloaddition Reactions of Carbonyls and Functionalized Imines with Alkenes"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Electro- and Photocatalytic Nitrogen Fixation using Molecular Catalysts"
11:30 am - 11:45 am
Discussion
11:45 am - 11:55 am
"Iron-Catalyzed Ring Opening Metathesis Polymerization of Olefins"
11:55 am - 12:00 pm
Discussion
12:00 pm - 12:10 pm
"Tethered Thioether Coordination as a Control Element on Rh(II)-Catalyzed Cyclopropanation"
12:10 pm - 12:15 pm
Discussion
12:25 pm - 12:35 pm
"C-H Functionalization Through Cu(II)/Cu(III) Redox Couple"
12:30 pm - 1:30 pm
Lunch
12:35 pm - 12:40 pm
Discussion
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Early-Career Investigator Presentations
7:30 pm - 8:00 pm
"Stereoselective C–H Insertion Reactions of Vinyl Carbocations and Electron Diffraction as a Molecular Characterization Method."
8:00 pm - 8:10 pm
Discussion
8:10 pm - 8:40 pm
"C-C s-Bond Oxidative Addition and Hydrofunctionalization by a Macrocycle-Supported Diiron Complex"
8:40 pm - 8:50 pm
Discussion
8:50 pm - 9:20 pm
"Achieving Oxygen Stable Electrochemical CO2 Capture and Concentration"
9:20 pm - 9:30 pm
Discussion
Wednesday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
9:00 am - 9:30 am
"Alleviating Strain in Organic Molecules by Incorporation of Phosphorus"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Carbenes and Dithiolene Radicals: Counterintuitive Main Group Chemistry"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"Dispersion Energy Donor Effects In Large Hydrocarbon Substituted Ligands"
11:30 am - 11:45 am
Discussion
11:45 am - 11:55 am
"Nontrigonal Phosphines Unlock New Metal-Ligand Cooperativity in Bond Activations"
11:55 am - 12:00 pm
Discussion
12:00 pm - 12:10 pm
"Atomically Precise Nanoclusters with an Edge: Molecular Insights into Single Atom Catalysts"
12:10 pm - 12:15 pm
Discussion
12:15 pm - 12:25 pm
"Catalyst Design in Olefin Polymerization Using High-Throughput Experimentation Tools and DFT QSPR Modeling: Development of Low-Dimensional 3D-Descriptors Allowing Catalyst Class Independent Models"
12:25 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Organometallic Chemistry at Surfaces
7:30 pm - 8:00 pm
"Toward a New Direct Process: Synthesis of Methylmethoxysilanes from Dimethyl Carbonate and Pentacopper Silicide"
8:00 pm - 8:10 pm
Discussion
8:10 pm - 8:40 pm
"Harnessing Metal Support Interactions in Organometallic Heterogeneous Catalysts"
8:40 pm - 8:50 pm
Discussion
8:50 pm - 9:20 pm
"Chemical Shifts Beyond Numbers: What We Can Learn About and from Organometallic Species"
9:20 pm - 9:30 pm
Discussion
Thursday
7:30 am - 8:30 am
Breakfast
8:30 am - 9:00 am
Business Meeting
Nominations for the Next Vice Chair(s); Complete the GRC Evaluation Forms; Discuss Future Dates and Venue; Election of the Next Vice Chair(s)
9:00 am - 12:30 pm
Bond Activation and Functionalization
9:00 am - 9:30 am
"Harnessing Non-Covalent Interactions to Address Selectivity Challenges in Transition Metal Catalysis"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
"Data Science Meets Organometallic Catalysis"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
"A New Catalytic Paradigm for Aliphatic Hydrogen Isotope Exchange with Tritium Gas"
11:30 am - 11:45 am
Discussion
11:45 am - 11:55 am
"Mechanistic Studies on Bi-Catalyzed Transfer Hydrogenation"
11:55 am - 12:00 pm
Discussion
12:00 pm - 12:10 pm
"Mechanistic Study of Oxidation-Induced N-N Coupling of Diazatitanacycles"
12:10 pm - 12:15 pm
Discussion
12:15 pm - 12:25 pm
"Rare-Earth Bis(phosphine-oxide)methanides – Cooperative Reactivity & Divergent Initiation Mechanisms to Access High-Performance Biodegradable Polymers"
12:25 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
7:30 pm - 7:40 pm
General Discussion
7:40 pm - 8:20 pm
"The Organometallic Chemistry of Cobalt Catalyzed C-H Functionalization"
8:20 pm - 8:35 pm
Discussion
8:35 pm - 9:15 pm
"Call a Copper! Fluoroalkylation of Organic Electrophiles using Fluoroalkenes."
9:15 pm - 9:30 pm
Discussion
Friday
7:30 am - 8:30 am
Breakfast
9:00 am
Departure