Sunday
2:00 pm - 9:00 pm
Arrival and Check-in
6:00 pm - 7:00 pm
Dinner
7:30 pm - 7:40 pm
Introductory Comments by GRC Site Staff / Welcome from the GRC Chair
7:40 pm - 9:30 pm
Bioorganometallic and Organometallic Chemistry
Discussion Leader: Paula Diaconescu (University of California, Los Angeles, United States)
7:40 pm - 8:15 pm
Hannah Shafaat (Ohio State University, United States)
"Prebiotic Chemistry in a Metalloprotein Model of Acetyl Coenzyme A Synthase"
8:15 pm - 8:30 pm
Discussion
8:30 pm - 9:05 pm
Odile Eisenstein (CNRS and Université de Montpellier, France)
"The Grignard Reagent and Reaction: A Cold Case With New Insights From Computations"
9:05 pm - 9:20 pm
Discussion
9:20 pm - 9:30 pm
General Discussion
Monday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Late and Heavy Metal Chemistry
Discussion Leader: Christine Thomas (The Ohio State University, United States)
9:00 am - 9:30 am
Aaron Tondreau (Los Alamos National Laboratory, United States)
"From Iron to Neptunium: Using Metals To Impart Selectivity on Ligand Synthesis"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
Vincent Lavallo (University of California, Riverside, United States)
"Fishing with Carborane Anions: New Ligand Platforms and Directions"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
Jennifer Schomaker (University of Wisconsin-Madison, United States)
"Taming Nitrene Reactivity with Silver Catalysts"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
Aaron Sadow (Iowa State University, United States)
"Organometallic Catalysts and Intermediates in CH and CC Bond Cleavage for Deconstructive Upcycling of Polyolefins"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
3:00 pm - 4:00 pm
The GRC Power Hour™
The GRC Power Hour™ is designed to address diversity and inclusion in the scientific workplace by providing a safe environment for informal and meaningful conversations amongst colleagues of all career stages. The program supports the professional growth of all members of our communities, including ethnicity, race and/or gender identity by providing an open forum for discussion and mentoring.
Organizers: Nancy Williams (Claremont McKenna, Scripps, and Pitzer Colleges, United States) and Jenny Yang (University of California, Irvine, United States)
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Harnessing Photons and Electrons
Discussion Leader: John Gordon (Los Alamos National Laboratory, United States)
7:30 pm - 8:00 pm
Louise Berben (University of California, Davis, United States)
"Metal Cluster Electrocatalysts For Fast and Selective Solar Fuels Chemistry"
8:00 pm - 8:10 pm
Discussion
8:10 pm - 8:40 pm
Yogesh Surendranath (Massachusetts Institute of Technology, United States)
"Electrical Polarization Controls Heterogeneous Hydride Transfer Reactivity"
8:40 pm - 8:50 pm
Discussion
8:50 pm - 9:20 pm
Daniel Nocera (Harvard University, United States)
"Harnessing Photons and Electrons for Farmers: Only?"
9:20 pm - 9:30 pm
Discussion
Tuesday
7:30 am - 8:30 am
Breakfast
8:30 am - 9:00 am
Group Photo
9:00 am - 12:30 pm
Synthesis and Catalysis with More Abundant Metals
Discussion Leaders: Peter Wolczanski (Cornell University, United States)
9:00 am - 9:30 am
Kyle Lancaster (Cornell University, United States)
"Covalency Consequences"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
Corinna Schindler (University of Michigan, United States)
"New Cycloaddition Reactions of Carbonyls and Functionalized Imines with Alkenes"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
Jonas Peters (California Institute of Technology, United States)
"Electro- and Photocatalytic Nitrogen Fixation using Molecular Catalysts"
11:30 am - 11:45 am
Discussion
11:45 am - 11:55 am
Satoshi Takebayashi (Okinawa Institute of Science and Technology Graduate University, Japan)
"Iron-Catalyzed Ring Opening Metathesis Polymerization of Olefins"
11:55 am - 12:00 pm
Discussion
12:00 pm - 12:10 pm
Ampofo Darko (University of Tennessee, United States)
"Tethered Thioether Coordination as a Control Element on Rh(II)-Catalyzed Cyclopropanation"
12:10 pm - 12:15 pm
Discussion
12:25 pm - 12:35 pm
Shiyu Zhang (The Ohio State University, United States)
"C-H Functionalization Through Cu(II)/Cu(III) Redox Couple"
12:30 pm - 1:30 pm
Lunch
12:35 pm - 12:40 pm
Discussion
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Early-Career Investigator Presentations
Discussion Leader: Thomas Cundari (University of North Texas, United States)
7:30 pm - 8:00 pm
Hosea Nelson (Caltech, United States)
"Stereoselective C–H Insertion Reactions of Vinyl Carbocations and Electron Diffraction as a Molecular Characterization Method."
8:00 pm - 8:10 pm
Discussion
8:10 pm - 8:40 pm
Neil Tomson (University of Pennsylvania, United States)
"C-C s-Bond Oxidative Addition and Hydrofunctionalization by a Macrocycle-Supported Diiron Complex"
8:40 pm - 8:50 pm
Discussion
8:50 pm - 9:20 pm
Jenny Yang (University of California, Irvine, United States)
"Achieving Oxygen Stable Electrochemical CO2 Capture and Concentration"
9:20 pm - 9:30 pm
Discussion
Wednesday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Main Group Chemistry
Discussion Leader: Nora Radu (DuPont, United States)
9:00 am - 9:30 am
Christopher Cummins (Massachusetts Institute of Technology, United States)
"Alleviating Strain in Organic Molecules by Incorporation of Phosphorus"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
Gregory Robinson (University of Georgia, United States)
"Carbenes and Dithiolene Radicals: Counterintuitive Main Group Chemistry"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
Philip Power (U of California, United States)
"Dispersion Energy Donor Effects In Large Hydrocarbon Substituted Ligands"
11:30 am - 11:45 am
Discussion
11:45 am - 11:55 am
Myles Drance (Massachusetts Institute of Technology, United States)
"Nontrigonal Phosphines Unlock New Metal-Ligand Cooperativity in Bond Activations"
11:55 am - 12:00 pm
Discussion
12:00 pm - 12:10 pm
Alexandra Velian (University of Washington, United States)
"Atomically Precise Nanoclusters with an Edge: Molecular Insights into Single Atom Catalysts"
12:10 pm - 12:15 pm
Discussion
12:15 pm - 12:25 pm
Christian Ehm (University of Naples, Federico II., Italy)
"Catalyst Design in Olefin Polymerization Using High-Throughput Experimentation Tools and DFT QSPR Modeling: Development of Low-Dimensional 3D-Descriptors Allowing Catalyst Class Independent Models"
12:25 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Organometallic Chemistry at Surfaces
Discussion Leader: Odile Eisenstein (CNRS and Université de Montpellier, France)
7:30 pm - 8:00 pm
John Roberts (Dow Inc., United States)
"Toward a New Direct Process: Synthesis of Methylmethoxysilanes from Dimethyl Carbonate and Pentacopper Silicide"
8:00 pm - 8:10 pm
Discussion
8:10 pm - 8:40 pm
Matthew Conley (University of California, Riverside, United States)
"Harnessing Metal Support Interactions in Organometallic Heterogeneous Catalysts"
8:40 pm - 8:50 pm
Discussion
8:50 pm - 9:20 pm
Christophe Coperet (ETH Zurich, Switzerland)
"Chemical Shifts Beyond Numbers: What We Can Learn About and from Organometallic Species"
9:20 pm - 9:30 pm
Discussion
Thursday
7:30 am - 8:30 am
Breakfast
8:30 am - 9:00 am
Business Meeting
Nominations for the Next Vice Chair(s); Complete the GRC Evaluation Forms; Discuss Future Dates and Venue; Election of the Next Vice Chair(s)
9:00 am - 12:30 pm
Bond Activation and Functionalization
Discussion Leader: John Walzer (OTORO Energy Inc., United States)
9:00 am - 9:30 am
Robert Phipps (University of Cambridge, United Kingdom)
"Harnessing Non-Covalent Interactions to Address Selectivity Challenges in Transition Metal Catalysis"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
Matthew Sigman (University of Utah, United States)
"Data Science Meets Organometallic Catalysis"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
Haifeng Yang (Merck & Co., Inc., United States)
"A New Catalytic Paradigm for Aliphatic Hydrogen Isotope Exchange with Tritium Gas"
11:30 am - 11:45 am
Discussion
11:45 am - 11:55 am
Hye Won Moon (Max-Planck-Institut für Kohlenforschung, Germany)
"Mechanistic Studies on Bi-Catalyzed Transfer Hydrogenation"
11:55 am - 12:00 pm
Discussion
12:00 pm - 12:10 pm
Yukun Cheng (University of Minnesota, United States)
"Mechanistic Study of Oxidation-Induced N-N Coupling of Diazatitanacycles"
12:10 pm - 12:15 pm
Discussion
12:15 pm - 12:25 pm
Jerome Robinson (Brown University, United States)
"Rare-Earth Bis(phosphine-oxide)methanides – Cooperative Reactivity & Divergent Initiation Mechanisms to Access High-Performance Biodegradable Polymers"
12:25 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Ligands and Metals
Discussion Leader: Heather Spinney (Dow, United States)
7:30 pm - 7:40 pm
General Discussion
7:40 pm - 8:20 pm
Paul Chirik (Princeton University, United States)
"The Organometallic Chemistry of Cobalt Catalyzed C-H Functionalization"
8:20 pm - 8:35 pm
Discussion
8:35 pm - 9:15 pm
R. Tom Baker (University of Ottawa, Canada)
"Call a Copper! Fluoroalkylation of Organic Electrophiles using Fluoroalkenes."
9:15 pm - 9:30 pm
Discussion
Friday
7:30 am - 8:30 am
Breakfast
9:00 am
Departure