Sunday
2:00 pm - 9:00 pm
Arrival and Check-in
6:00 pm - 7:00 pm
Dinner
7:30 pm - 7:40 pm
Introductory Comments by GRC Staff / Welcome and Introduction from the Chairs
7:40 pm - 9:30 pm
Organometallic Chemistry of the Lanthanides and Actinides
Discussion Leader: Stosh Kozimor (Los Alamos National Laboratory, United States)
7:40 pm - 8:20 pm
Suzanne Bart (Purdue University, United States)
"Organometallic Chemistry at the Bottom of the Periodic Table"
8:20 pm - 8:35 pm
Discussion
8:35 pm - 9:15 pm
Karsten Meyer (Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Germany)
"Photocrystallographic Formation of an Authenticated cis-Dioxo Uranium Complex"
9:15 pm - 9:30 pm
Discussion
Monday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Early-Career Investigator Presentations
Discussion Leader: Neal Mankad (University of Illinois at Chicago, United States)
9:00 am - 9:30 am
Amanda Cook (University of Oregon, United States)
"Oxidative Addition of Silyl Hydrides and Silyl Halides to Pd(0)"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
Robert Comito (University of Houston, United States)
"Bimetallic Main-Group Catalysts for the Synthesis of Advanced Biodegradable Polymers"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
Allegra Liberman-Martin (Chapman University, United States)
"Catalytic Activity of Zerovalent Carbon Compounds"
11:30 am - 11:45 am
Discussion
11:45 am - 12:15 pm
Alex Nett (Dow Chemical Company, United States)
"The Development of [P,O]-Nickel Catalysts for Ethylene/Acrylate Copolymerization"
12:15 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
3:00 pm - 4:00 pm
The GRC Power Hour™
The GRC Power Hour™ is designed to address diversity and inclusion in the scientific workplace by providing a safe environment for informal and meaningful conversations amongst colleagues of all career stages. The program supports the professional growth of all members of our communities, including ethnicity, race and/or gender identity by providing an open forum for discussion and mentoring.
Organizers: Jessica Klinkenberg (DuPont, United States) and Nancy Williams (Claremont McKenna, Scripps, and Pitzer Colleges, United States)
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Organometallic Materials and Polymers
Discussion Leader: Mari Rosen (The Dow Chemical Company, United States)
7:30 pm - 8:00 pm
Alexandra Velian (University of Washington, United States)
"Molecular Catalysts Go Nano: Installing Active Sites on Clusters and Nanosheets"
8:00 pm - 8:10 pm
Discussion
8:10 pm - 8:40 pm
David Kaphan (Argonne National Laboratory, United States)
"Metal-Surface Electronic Communication in Surface Organometallic Catalysis"
8:40 pm - 8:50 pm
Discussion
8:50 pm - 9:20 pm
Aleksandr Zhukhovitskiy (University of North Carolina at Chapel Hill, United States)
"Synthesis of Heteroatom-Rich Polymers: New Strategies and Organometallic Mechanisms"
9:20 pm - 9:30 pm
Discussion
Tuesday
7:30 am - 8:30 am
Breakfast
8:30 am - 9:00 am
Group Photo
9:00 am - 12:30 pm
Applications of Organometallic Chemistry in Organic Synthesis
Discussion Leader: Jessica Klinkenberg (DuPont, United States)
9:00 am - 9:30 am
Sophie Rousseaux (University of Toronto, Canada)
"New Developments in Ni-Catalyzed Reductive Cyanation"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
Caleb Hethcox (Merck , United States)
"Development of a Nickel-Catalyzed Sulfonylation Process for the Manufacture of Belzutifan"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:45 am
Melanie Sanford (University of Michigan, United States)
"Alexander M. Cruickshank Lecture: Adventures in High Valent Organometallic Complexes Relevant to Catalysis"
11:45 am - 12:00 pm
Discussion
12:00 pm - 12:10 pm
Kyle Pearce (University of Bath, United Kingdom)
"Beryllium-Centred C-H Activation of Benzene"
12:10 pm - 12:15 pm
Discussion
12:15 pm - 12:25 pm
Gaël Ung (University of Connecticut, United States)
"Improving Circularly Polarized Luminescence Metrics"
12:25 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Main Group Chemistry and Catalysis
Discussion Leader: Glen Alliger (ExxonMobil Chemical, United States)
7:30 pm - 8:00 pm
Robert Gilliard (Massachusetts Institute of Technology, United States)
"Uncommon Bonds at Boron: Counterintuitive Approaches Toward Luminescent Molecular Materials"
8:00 pm - 8:10 pm
Discussion
8:10 pm - 8:40 pm
Roland Roesler (University of Calgary, Canada)
"Chelating Bis(N-Heterocyclic Carbenes) with Flexible Backbones for the Stabilization of Reactive Species"
8:40 pm - 8:50 pm
Discussion
8:50 pm - 9:20 pm
Josep Cornella (Max-Planck-Institut fuer Kohlenforschung, Germany)
"Tales on Bismuth Redox Catalysis"
9:20 pm - 9:30 pm
Discussion
Wednesday
7:30 am - 8:30 am
Breakfast
9:00 am - 12:30 pm
Ligand Design
Discussion Leader: Christopher Uyeda (Purdue University, United States)
9:00 am - 9:30 am
Kensha Clark (University of Mississippi, United States)
"Enabling the Unexpected with Ligands: Methane Activation and More with d 10 Metal Centers"
9:30 am - 9:40 am
Discussion
9:40 am - 10:10 am
Ba Tran (Pacific Northwest National Laboratory, United States)
"Influence of Geometry and Nuclearity on the Chemistry of Copper Hydrides"
10:10 am - 10:20 am
Discussion
10:20 am - 10:55 am
Coffee Break
10:55 am - 11:25 am
Natalie Fey (University of Bristol, United Kingdom)
"Leveraging Data in Organometallic Catalysis"
11:25 am - 11:35 am
Discussion
11:35 am - 12:05 pm
Tiow-Gan Ong (Academia Sinica, Taiwan)
"The Science of Carbone with its Elusive Bonding Description and Broad Implication Complementary to NHC-Carbenes"
12:05 pm - 12:15 pm
Discussion
12:15 pm - 12:25 pm
Konstantin Bukhryakov (Florida International University, United States)
"Vanadium Alkylidenes for Olefin Metathesis"
12:25 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Transition Metal Chemistry and Catalysis
Discussion Leader: Maurice Brookhart (University of Houston, United States)
7:30 pm - 7:40 pm
Nicola L Bell (University of Glasgow, United Kingdom)
"AutoSchlenk: Digital Organometallic Chemistry"
7:40 pm - 7:45 pm
Discussion
7:45 pm - 7:55 pm
Patrick Kelly (University of Chicago, United States)
"A Synthetic Cycle for Heteroarene Synthesis by Nitride Insertion"
7:55 pm - 8:00 pm
Discussion
8:00 pm - 8:30 pm
Kyoko Nozaki (University of Tokyo, Japan)
"Neighboring-Group Effect in Homogeneous Catalysis: Non-innocence of Supporting Ligands and Counter Ions"
8:30 pm - 8:45 pm
Discussion
8:45 pm - 9:15 pm
Stefan Mecking (University of Konstanz, Germany)
"Organometallic Catalysis Enabling Closed-Loop Recyclable and Non-Persistent Polyolefin-Like Materials"
9:15 pm - 9:30 pm
Discussion
Thursday
7:30 am - 8:30 am
Breakfast
8:30 am - 9:00 am
Business Meeting
Nominations for the Next Vice Chair(s); Complete the GRC Evaluation Forms; Discuss Future Dates and Venue; Election of the Next Vice Chair(s)
9:00 am - 12:30 pm
Energy and the Environment
Discussion Leader: Max Delferro (Argonne National Laboratory, United States)
9:00 am - 9:30 am
Caroline Saouma (University of Utah, United States)
"Thermochemical Considerations for CO2 Reduction"
9:30 am - 9:45 am
Discussion
9:45 am - 10:15 am
Susannah Scott (University of California, Santa Barbara, United States)
"Designing Heterogeneous Catalysts for Upgrading Renewable and Recycled Carbon"
10:15 am - 10:30 am
Discussion
10:30 am - 11:00 am
Coffee Break
11:00 am - 11:30 am
Nilay Hazari (Yale University, United States)
"Fundamental Studies of Hydride Transfer Reactions Relevant to Energy Storage"
11:30 am - 11:45 am
Discussion
11:45 am - 11:55 am
Emily Tsui (University of Notre Dame, United States)
"Sulfur Effects on Zinc Thiolate Nucleophilicity"
11:55 am - 12:00 pm
Discussion
12:00 pm - 12:10 pm
Matthew Chambers (Louisiana State University, United States)
"Direct Light-Initiated C–H Functionalization by Group VI Metal Dioxo Complexes"
12:10 pm - 12:15 pm
Discussion
12:15 pm - 12:25 pm
Jamie Neely (Saint Louis University, United States)
"Iron-Mediated Multicomponent Coupling Strategies via Iron Azametallacyclobutenes"
12:25 pm - 12:30 pm
Discussion
12:30 pm - 1:30 pm
Lunch
1:30 pm - 4:00 pm
Free Time
4:00 pm - 6:00 pm
Poster Session
6:00 pm - 7:00 pm
Dinner
7:30 pm - 9:30 pm
Keynote Session: Mechanistic Organometallic Chemistry
Discussion Leader: Paula Diaconescu (University of California-Los Angeles, United States)
7:30 pm - 8:15 pm
Karen Goldberg (University of Pennsylvania, United States)
"An Organometallic Compound and an Oxygen Molecule Walk into a Bar…"
8:15 pm - 8:30 pm
Discussion
8:30 pm - 9:15 pm
Clark Landis (University of Wisconsin-Madison, United States)
"One Way or Another: Stereochemical Outcomes in Transition-Metal Catalyzed Alkene Functionalization"
9:15 pm - 9:30 pm
Discussion
Friday
7:30 am - 8:30 am
Breakfast
9:00 am
Departure